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In the literature, the specific patterns of main pigment fragments have been reported, unfortunately sometimes lacking unidentified fragments or smaller molecules with toxicological relevance Chiantore et al.
Losing some unique fragments makes identification of pigments more challenging though.
Additionally, applied pyrolysis temperatures greatly vary between publications. Therefore, we tested the influence of different temperatures on the thermal stability of various pigments. The feasibility of this pyrogram library was then tested on 28 commercially available tattoo inks from different German and international manufacturers.
Additionally, 18 self-made pigment mixtures were used to appraise limitations of the method. The pyrolysis products presented in this paper were also reviewed for their toxicological properties. Recent studies have provided evidence that products of pyrolysis will be comparable to those obtained by laser irradiation Engel et al.
Hence, the compiled pyrolysis fragments might be suitable to predict hazardous decomposition products of organic pigments that possibly evolve during laser irradiation or sunlight exposure of tattooed skin. Shellac was obtained as food-grade and orange shellac from Kremer Pigmente Aichstetten, Germany.
For tattoo inks, a solvent vent method was used to dry the samples and to analyze for semi-volatile compounds prior to the onset of pyrolysis. Therefore, the TDU was ramped after 0. The solvent vent quit after 1. Data were analyzed using Enhanced ChemStation E In this case, matches with scores higher than 90 were accounted true. If a pigment was in stock from more than one supplier, only mutual peaks of the respective pyrograms were depicted in Tables S1— The pigments investigated were chosen according to their popularity in use for tattoo inks taken from ink declarations and published surveys BAG ; CVUA Areas of the extracted molecular mass ions, normalized to the total chromatogram area, were found increasing and thus confirm the expected temperature-dependent formation of decomposition products Fig.
Some pigments, such as pigment orange P. On the other hand, extremely stable pigments such as pigment violet P. Open image in new window Fig. Degradation of pigments is indicated by carbonization of the test tubes a and the increase in cleavage products b.
The onsets of decoloration and carbonization were indicated with dashed and solid lines, respectively. Since the occurrence of such as yet unknown molecule descendants is unique to certain pigments, we added these fragments as unknowns to the lists of decomposition products. In the following, all different classes of organic pigments used in tattoo inks are discussed in terms of their main pyrolysis products and accompanying toxicological hazards.
Phthalocyanines 1,2-Benzenedicarbonitrile and its halogenated derivatives are the most abundant products emerging upon pyrolysis of the phthalocyanines P.
Because these molecules do not occur in the pyrograms of any other pigment analyzed, they can be used for the identification of phthalocyanines. In addition, benzonitrile and phthalimide result from pyrolysis of P. Since the latter compound is used in the synthesis of the pigment, its presence likely indicates incomplete purification.
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Traditional and Modern Styles, Munich, Reuss gives an insight into the Japanese tattoo scene a decade ago. Accessed June 24, I should meet many more of these customers while getting tattooed by Horihiro in the following months and had the possibility to interview some members of the Yamaguchi gumi, the biggest syndicate in Japan with its headquarters in Kobe. The customers were predominantly men, entering the studio, introducing themselves and providing a business card that informed about the rank and geographical location within the syndicate.
They usually just stated that they wanted to be tattooed.
My yakuza interview partners told me, that there is no necessity to get a tattoo when becoming a member of a yakuza branch, but most of them would do to express their status and financial wealth. Nevertheless, the customer in such cases usually has no real influence on the final design. The tattoo master usually proposes some possible designs based on his impression of the customer, very often working with antagonist images, which means that a strong person would rather get a weaker tattoo image and vice versa.
Again, the heroes of the Suikoden are still very popular today.
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Usually, the tattoo artist then also proposes which kind of background should be used for the art work. Traditionally, there are specific options for this purpose: peonies, cherry blossoms, or autumn leaves.
In addition, the background usually follows, from bottom to top of the body, the natural order of water, ground, sky, which means for a traditional bodysuit that the legs would be covered with waves and animals from the oceans and rivers, while the arms and upper body could follow the named natural order as! Overall, the design is based on the ideas and preferences of the tattoo master. Session by session the tattoo becomes more and more impressive, while the body is changed step by step as well.
Asked why they chose to be tattooed in such an extensive way, most customers answered that they liked the aesthetics the body would gain from a tattoo. Some just mentioned that they had seen such tattoos before and were impressed by them, why they eventually decided to get one as well. During the sessions with Horihiro I learned a lot about the traditional tattoo artists in the Osaka region, whose number was rather small, while depending on a specific group of customers, i.
Foreign tourists and younger customers, inspired by the Western tattoo scene, would probably rather frequent one of the modern tattoo parlors, which Japan in general, and Osaka in particular, also has to offer.
There, the traditional values might be known by some tattoo artists, especially those who are interested in or deal with Japanese tattoos wabori and fuse them with modern elements, like Genko27 and Sabado28 in Nagoya, but customers might rather choose Western old school designs. He said he liked to work on traditional images, yet would try to reinterpret them into his own style, instead of copying the traditional rules too accurately.
Most of the younger customers liked oldschool or graphity style tattoos and were not interested in the too traditional designs anyway. When askey why they got tattooed, many of them simply replied that they wanted to be different, or express individualism. Like the people in Tokugawa Japan, those people who get tattooed today in a way rebel against the norms of Japanese society, which demand conformity.
This might be why some of the customers chose not to hide their tattoos, but request them to be extremely visible, e. Therefore, the rebellion against the coformity of the body, as described by Barthes, is also visible for others.
The modification of the self therefore becomes a rebellion against the social norms per se, although the design is rather Western, to make sure not to be mistakenly considered part of the Japanese underworld.
For the Japanese public, however, it does not really seem to matter if one is part of the traditional or rather Western faction. Tattoos are considered a disruption of the so often demanded social conformity.
Japan has no heart or place for outsiders at all. It is funny to see, that the outsiders, no! Often, there is miscommunication. Every tattoo has a meaning and usually a story. While the first one could be deciphered by an outsider, the story is usually unknown until shared by the tattooed person him- or herself. The reasons to get a tattoo are countless, as are the designs that are possible today. If you know what you want, know how you want it but don't have the necessary artwork material, then our tattoo collections will come in real handy.
Just download the best collections for you and let your creativity fly. Sit down with your friends or consult with your tattoo artist to build something amazing.
After downloading, we highly recommend you to print everything, so you can see all the components while working. You can also cut out the designs and try some quick arrangements for a better view. You will need a photo editor capable of working with layers, this will make everything easier. You can copy-paste all the selected designs on new layers in a blank file. This way you can move, rotate, scale and edit each object separately.
You can use layer blending modes and set it to "Darken" or "Multiply" to get rid of the white background and see the dotwork content only.Rhodamine B C. Shellac was obtained as food-grade and orange shellac from Kremer Pigmente Aichstetten, Germany. Hence, the compiled pyrolysis fragments might be suitable to predict hazardous decomposition products of organic pigments that possibly evolve during laser irradiation or sunlight exposure of tattooed skin.
In the following, all different classes of organic pigments used in tattoo inks are discussed in terms of their main pyrolysis products and accompanying toxicological hazards. While the character for dog was used in Hiroshima prefecture top left , in Chikuzen modern Fukuoka and Awa nowaday Tokushima province top right and middle the tattoo design was rather pragmatic, using a stroke for every crime committed by the convict. During the late Tokugawa period two groups were wearing larger tattoos jap.
This style is used to obtain delicate looks. The reasons to get a tattoo are countless, as are the designs that are possible today. The quinophthalone P. In the case of TIF, the molecule abundance even strongly decreased at higher temperatures.
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